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Q.

Identify the incorrect statements among the following?

i. SF6 does not react with water

ii. SF6 is  SP3  hybridized

iii.  S2O32i s a linear ion

iv. There is no π-bonding in SO42 ion

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a

( ii),(iii) and (iv)

b

(iii) and (iv)

c

(i),(ii) and (iii)

d

(i) and (ii)

answer is A.

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Detailed Solution

(α) InSF6, the sulphur atom is shielded by 6 fluorine atoms which hinders kinetically any reaction with water, alkali hydroxide, ammonia or strong acid, as a result, it remains inert to these reagents. SF6 contain 6 steric number and sp3d2 hybridization

S2O32  is similar look like ammonia shape  

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