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Q.

Identify the metals (M) in the complexes given in column – I and match the complexes with their characteristic property (properties) given in column – II

 Column – I Column – II
AEAN for [M(H2O)6]3+ is 36PParamagnetic complex
BEAN for [M(H2O)6]2+ is 33QDiamagnetic complex
CEAN for [M(NH3)6]3+ is 35RThe value of spin only magnetic moment is equal to corresponding fluoro complex
DEAN for [M(NH3)4]2+ is 36SThe value of spin only magnetic moment is equal to corresponding cyano complex

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a

A-PRS; B-QS; C-QRS; D-PS

b

A – QPS; B –PR; C –QRS; D – PS

c

A-QS; B-PRS; C-PS; D-QRS

d

A-PR; B-S; C-PRS; D-QR

answer is D.

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Detailed Solution

A=[Co(H2O)6]3+, B=[V(H2O)6]2+, C=[Fe(NH3)6]3+, D=[Zn(NH3)4]2+

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