Q.

Identify the option having the correct relation between a and b, if it is known that for hydrogen gas

CpCv=a and also for oxygen gas CpCv=b (Cp and Cv are molar specific heats at constant pressure and constant volume respectively)

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a

a = b

b

a = 16b

c

a = 4b

d

b = 16a

answer is D.

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Detailed Solution

At constant pressure

dQ=μCpdT,dU=μCVdT;dW=μRdTdQ=dU+dWμCpdT=μCVdT+μRdTCpCv=R

On equation both the given equations, we get a = b

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