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Q.

Identify the option representing correct set of true/false statements :

Statement-1: TiO3 can behave as conductor or insulator depending upon temperature.
Statement-2: CrO2 has electrical properties like metals.

Statement-3: AgBr can show both Frenkel as well as Schottky defects.

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a

All the statements are correct

b

Only statement-3 is correct

c

Only statement-I is incorrect

d

Only statement-2 is correct

answer is A.

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Detailed Solution

Because the energy difference between the valence band and conduction band changes with temperature, TiO3 either behaves as a conductor or an insulator depending on the temperature.

Some common metal oxides, including CrO2, have similar electrical conductivity as metal.

AgBr's intermediate radius ratio causes it to exhibit both Frenkel and Schottky faults. When both of the ion's anions and cations are missing from the crystal lattice, the ions have Schottky defects. Because the Ag+ and Br- ions are missing from the crystal lattice in AgBr, Schottky defects result.

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Identify the option representing correct set of true/false statements :Statement-1: TiO3 can behave as conductor or insulator depending upon temperature.Statement-2: CrO2 has electrical properties like metals.Statement-3: AgBr can show both Frenkel as well as Schottky defects.