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Q.

Identify the pair of lanthanoides with one strong oxidation and one strong reduction

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a

Yb(III),Eu(II)

b

Ce(IV),Tb(IV)

c

Eu(IV),Lu(III)

d

Ce(IV),Eu(II)

answer is C.

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Detailed Solution

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 63Eu=[Xe]4f76s2
Eu2+ is a strong reducing agent changing to common +3 state.
 58Ce=[Xe]4fl5d6s2Ce(IV) is a strong oxidant.E0ofCe4+/Ce3+=1.74V The Ero of Ce
suggests that it can oxidise water.

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