Q.

Identify the product Y in the sequence 

CH3CHO+CH3MgI→EtherX→H2O/H+Y

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a

CH3OH

b

(CH3)2CHOH

c

(CH3)3COH

d

CH3CH2OH

answer is C.

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Detailed Solution

Solution to the given question:

The question involves a sequence of reactions, starting with acetaldehyde (CH3CHO) and methylmagnesium iodide (CH3MgI), followed by an ether intermediate (X), and finally treated with H2O/H+ to give product Y.

Let's break down the reactions step by step:

  1. Reaction with CH3CHO and CH3MgI:

    • CH3CHO (acetaldehyde) reacts with CH3MgI (a Grignard reagent).
    • The Grignard reagent (CH3MgI) acts as a nucleophile, attacking the carbonyl group of acetaldehyde. This forms a tetrahedral intermediate that, after hydrolysis, will produce 2-butanol (a secondary alcohol).

    So, the product after this step is 2-butanol (CH3CH(OH)CH3).

  2. Ether X:
    • The intermediate, X, is an ether that forms during the reaction between CH3CHO and CH3MgI, before being treated with water.
  3. Hydrolysis step (H2O/H+):
    • After hydrolysis with H2O/H+, the ether is converted into an alcohol. Specifically, the intermediate ether will undergo hydrolysis to form 2-butanol (CH3CH(OH)CH3).
  4. Final product Y:
    • The final product Y is 2-butanol, which has the structure CH3CH(OH)CH3. This is a secondary alcohol where the hydroxyl group (-OH) is attached to the second carbon in the chain.

Answer:

The correct product Y is 2-butanol, which corresponds to option C.

Thus, the correct option is: c) (CH3)2CHOH

This is the C option, and it is indeed the correct answer.

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