Q.

Identify the reaction from following having top position in EMF series (Std. red. potential) according to their electrode potential at 298 K.

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a

Au3++3eAu(s)

b

Fe2++2eFe(s)

c

Mg2++2eMg(s)

d

K++1eK(s)

answer is D.

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Detailed Solution

Au3++3eAu(s)    E=1.40VFe2++2eFe(s)    E=0.44VMg2++2eMg(s)    E=2.36VK++1eK(s)    E=2.93V

As per electrochemical series, Au3+ occupies the top position.

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