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Q.

Identify the set of elements which do not exhibit multiple oxidation states

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a

Zn, Sc

b

Sc, Ti

c

Mn, Cr

d

Zn, Cr

answer is D.

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Detailed Solution

Scandium always exists in the oxidation state (+3), and occurs as Sc3+ ion

The formation of  requires the removal of Sc3+ the two 4s and one d-d spectrum is impossible. Consequently the ion and its compounds are colorless and diamagnetic. Of the simple ions of the 3d-serios, only Sc3+

is known to have  d0  configuration. Zn (+2) is the only state known for Zn. However the answer of this question is (4), because Zn is a d-block element but not a transition element. The reduced tendency of higher oxidation states towards the end of the series is due to steady increase in the effective nuclear charge along the series. This pulls the (n-1) d orbitals into the electron core and hence they are not readily available for bonding. For instance, the only oxidation state for Zn is Zn(+2) where no (n-1) d electron is involved. On the other hand, early in the series, it is difficult to form species that do not utillize the (n-1) d electron, e.g., Sc(+2) is virtually unknown while Ti(+4) is more stable than Ti(+2).

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Identify the set of elements which do not exhibit multiple oxidation states