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Q.

Identify the statement that is not correct as far as structure of diborane is concerned

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a

There are two bridging hydrogen atoms and four terminal hydrogen atoms in diborane

b

Each boron atom forms four bonds in diborane

c

The hydrogen atoms are not in the same plane in diborane

d

All B–H bonds in diborane are similar

answer is D.

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Detailed Solution

Bridged B-H bond lengths are greater than that of terminal B-H bond lengths.

Bond Length: B-Hb > B-Ht

→ Two BH2 groups are in one plane and two bridged hydrogens are in another plane.

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Identify the statement that is not correct as far as structure of diborane is concerned