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Q.

Identify (X), (Y) and (Z) reagents in the given sequence of reaction.

CHCHxCH3CHOyCH3CH(OH)CH3zCH3COCH3

 

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a

X=H2SO4/Hg2+;Y=PCl5/H2OZ=K2Cr2O7/OH-

b

X=H2SO4;Y=H2O/OH-;Z=PCl5, heat 

c

X=HNO3;Y=Na2CO3;Z=H2SO4, heat 

d

X=H2SO4/Hg2+;Y=CH3MgBr/H2O;Z=K2Cr2O7/H+

answer is D.

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Detailed Solution

detailed_solution_thumbnail

HCCHH2OHgSO4,dil.H+ CH3CHO CH3MgBr/H2O CH3CH(OH)CH3    CH3CH(OH)CH3 K2Cr2O7/H+ CH3COCH3

Hence, the correct option is (D)

X=H2SO4/Hg2+;Y=CH3MgBr/H2O;Z=K2Cr2O7/H+

 

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Identify (X), (Y) and (Z) reagents in the given sequence of reaction.CH≡CH⟶xCH3CHO⟶yCH3CH(OH)CH3⟶zCH3COCH3