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Q.

Identity the incorrect statement from the following

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a

All the five 5d orbitals are different in size when compared to the respective 4d orbitals.

b

In an atom, all the five 3d orbitals are equal in energy in free state.

c

The shapes of dxy,dyz and dzx orbitals are similar to each other ; and dx2-y2 and  dz2 are are similar to each other.

d

All the five 4d orbitals have shapes similar to the respective 3d orbitals 

answer is D.

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Detailed Solution

shape of dx2-y2 will differ from dz2 
dx2-y2  is double dumbell, but dz2 is not.
(1) For a given species, as ‘n’ value increases, radius of shell increases . Size of 5d >4d.
(2) Shape of orbital depends on ‘I’ value. For all d-orbital, ‘I’ value is same, shape of all d-orbitals is same
(3) d- orbitals are degenerate in free state 

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