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Q.

(IE)1 and (IE)2 of Mg(g) are 740, 1540 kJ mol-1. Calculate percentage of Mg+(g) and Mg2+(g) if 1 g of Mg(g) absorbs 50.0 kJ of energy.

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a

%Mg+ = 50% %Mg+2 = 50%

b

%Mg+ = 70.13% %Mg+2 = 29.87%

c

%Mg+ = 75% %Mg+2 = 25%

d

%Mg+ = 60% %Mg+2 = 40%

answer is B.

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Detailed Solution

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Energy supplied per gram  =  50KJ
Energy supplied per mole  =  (50x24)KJ
                                           =  1200 KJ
IP1 of "Mg" is 740 KJ/Mole
Thus all the gaseous "Mg" atoms completely get ionized to gaseous Mg+ ions by absorbing 740KJ ;

Of the 1200 KJ  energy supplied,
The energy still available = (1200-740)KJ
                                        = 460 KJ
Since IP2 of "Mg" is 1540 KJ/mole,
Mg+gMg+2g,100% conversion Occurs only when 1540 KJ of energy is supplied.
only 460KJ of energy is available, the % of conversion of Mg+gMg+2g will be

4601540×100=29.87%
Percentage Mg+2g = 29.87%
Percentage Mg+g   = 70.13%

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