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Q.

If $Δ_{0} < P$ , the correct electronic configuration for d⁴ system will be

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a

$t_{2}^{0} {ge}^{4}$

b

$t_{2}^{3} g_{g}^{1}$

c

$t_{2}^{2} {ge}_{g}^{2}$

d

$t_{2 g}^{4} e_{g}^{0}$

answer is B.

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Detailed Solution

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On the basis of crystal field theory, for a d⁴ ion, if Δ₀<P , then the complex is a high spin complex formed by the association of weak field ligands with the metal.
As a result the fourth electron enters one of the e_g orbitals, there by exhibiting the electronic configuration : t_2g³ e_g¹

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