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Q.

If 0.01 M solution of an electrolyte has a resistance of 40 ohms in a cell having a cell constant of 0.4 cm–1, then its molar conductance in ohm–1 cm2 mol–1 is

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a

102

b

104

c

10

d

103

answer is D.

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Detailed Solution

Molarity = 0.01 M ; Resistance = 40 ohm;

Cell constant lA=0.4cm1

Specific conductivity κ 

=cell constantresistance=0.440=0.01 ohm1cm1

Molar conductance (m)=1000κMolarity

=1000×0.010.01=103ohm1cm2mol1

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