Q.

If 100 mole of H2O2 decomposes at 1 bar and 300K, the work done (kJ) by one mole of  O2(g) as it expands against 1 bar pressure is:

2H2O2(l)2H2O(l)+O2(g) (R=8.3  JK1  mol1)

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a

124.50

b

249.00

c

498.00

d

62.25

answer is A.

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Detailed Solution

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2H2O2(l)2H2O(l)+O2(g) w=Pext(ΔV)=nO2RT

   100 mole  H2O2 on decomposition give 50 mole  O2

  w=(50)(8.3)(300)=124500J=124.5  kJ

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