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Q.

If 3-chloro 3 – methyl hexane is treated with C2H5ONa/C2H5OH, E2 Elimination reaction takes place predominantly. How many isomeric alkenes would be formed?

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answer is 5.

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Detailed Solution

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Step 1. Substrate
2-chloro-3-methylpentane is treated with sodium ethoxide (C₂H₅ONa) in ethanol.

 

Step 2. Mechanism
E2 elimination requires:

  • Strong base (EtO⁻).

  • Anti-periplanar β-hydrogen relative to the leaving group (Cl).
    Hydrogen from a β-carbon is abstracted, Cl leaves, and a double bond forms.

  •  

Step 3. Products
Three alkenes are formed:

  1. 2-methylpent-2-ene (major product, more substituted alkene → Zaitsev product).

  2. 3-methylpent-2-ene (possible due to β-H elimination from the other β-carbon).

  3. 3-methylpent-1-ene (minor, less substituted → Hofmann product).

  4.  

Step 4. Selectivity

  • Sodium ethoxide favors Zaitsev’s rule.

  • Major product = 2-methylpent-2-ene (most stable, internal alkene).

  •  

Final Answer:
The reaction is an E2 elimination of 2-chloro-3-methylpentane with EtONa/EtOH, yielding mainly 2-methylpent-2-ene, with minor 3-methylpent-2-ene and 3-methylpent-1-ene.

 

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