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Q.

If 30 g sample of a chloroplatinate salt of diacidic organic Lewis base on ignition produces 5 g of white residue, then what will be the molar mass of the base? [Pt=195]

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a

1170

b

760

c

410

d

380

answer is A.

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Detailed Solution

B230 gH2PtCl62ΔPt5.0 g

using POAC on Pt atom

mole of Pt in B2H2PtCCl62 = mole of Pt atom in Product

2× mole of B2H2PtCCl62= mole of Pt

30×22B+410×2=5195

B=760

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