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Q.

If a complex, ${Ma}_{4} b_{2}$ (where Mis a central atom and a and b are monodentate ligands) has trigonal prismatic geometry, the total number of possible geometrical isomers would be :

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a

2

b

3

c

4

d

5

answer is C.

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Detailed Solution

There are two geometrical isomers of ${Ma}_{4} b_{2}$ is shown in the figure,

Question Image

$\begin{aligned} b \to 3, 5 \\ b \to 3, 6 \\ b \to 1, 6 \end{aligned}$

Here, total number of possible geometrical isomers are 2.

Hence correct option is b.

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