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Q.

If A3+, B2+ and C+ reduce at cathode in different experiments. If equal charge provided to each ion and charge to mass ratio of each ion is same, the select the correct statement.

[Assume that the efficiency is 100% for each experiment and A3+, B2+ and C+ reduce to A, B and C respectively ] 

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a

Mass deposit of A is maximum among all three ions

b

 Mass deposit of B is maximum among all three ions

c

Mass deposit of C is maximum among all three ion

d

Same mass of A, B and C deposit

answer is D.

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Detailed Solution

According to Faraday's second law of electrolysis  ''The masses of different ions liberated at the electrodes, when the same amount of electricity is passed through the electrolytic solution are directly proportional to their respective chemical equivalent weights”.

If equal charge is given then equal number of equivalent get deposited. 

In the given problem, equal charge is supplied to each ion and each ion has the same charge/mass ratio. This depicts that same mass of A, B, and C deposit.

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