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Q.

If Agl crystallizes in the ccp, zinc blende structure, assuming that I- ions occupy the lattice points, what fraction of tetrahedral voids is occupied by Ag+ ions?

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a

25% 

b

50%

c

100% 

d

75% 

answer is B.

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Detailed Solution

  • In Zinc Blende structure, anions are present at the lattice points while cations Ag+ are present in alternate tetrahedral voids and therefore, the fraction of tetrahedral voids occupied by Ag+ ions is 50%.
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