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Q.

If bond dissociation energies of xy,x2 and y2 (all diatomic molecules) are in the ratio of 1 : 1 : 0.5 and ΔHf for the formation of xy is200KJ  mol1, the bond dissociation energy of X2 will be:

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a

600 KJ/mol

b

300 KJ/mol   

c

200 KJ/mol

d

800 KJ/mol

answer is D.

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Detailed Solution

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X2+Y22XY

ΔH=(BE)xx+(BE)yy2(BE)xy

 If B.E of (xy)=a, then B.E. of (xx)=a

and B.E of (Yy)=a2

ΔH(xy)=200kJ

 400 ( for 2 moles of xy) =a+a22a

400=a2  or  =+800kJ

The bond dissociation energy of  x2=800kJ/mol

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