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Q.

If calcium and strontium are the first two members of the Dobereiner triads, which one is the third element?

(atomic masses are mentioned in the bracket below)

 [ Ca= 40 u, Sr= 87.6 u, Ba=137.23 u, Cs=132.9 u, Mg=24.3 u, Na=22.9 u ]

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a

Cesium

b

Magnesium 

c

Barium

d

Sodium

answer is C.

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Detailed Solution

 The atomic mass of calcium and strontium is 40 and  87.62

 Let us consider x as the third element.

 According to Dobereiner's triads rule-

40+x2=87.62

40+x=87.62×2

x=175.24-40

x=135.24 u

The value of x is approximately equal to the atomic mass of Barium.

Hence, we can say that the third element of this triad is 'Barium'.

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