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Q.

If CI2 gas is passed into aqueous solution of KI containing some CCl4 and the mixture is shaken then

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a

Lower layer becomes color less

b

upper layer becomes violet

c

homogenous violet layer is formed

d

lower layer becomes violet

answer is B.

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Detailed Solution

2KI+Cl22KCl+I2
I2+CCl4 Violet Colour 
Note: The excess of Cl2 should be avoided. The layer may become colourless due to conversion of I2 to HIO3
I2+5Cl2+6H2O2HIO3+10HCl
 In case of Br2:Br2+2H2O+Cl22HBrO+2HCl
The layer test is based upon distribution law

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