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Q.

If CO ligands are substituted by NO in respective neutral carbonyl compounds then which of the following will not be correct formula ?

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a

$Fe (CO)_{2} (NO)_{2}$

b

$Cr (CO)_{3} (NO)_{2}$

c

$Ni (CO)_{2} (NO)_{2}$

d

$Cr (NO)_{4}$

answer is D.

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Detailed Solution

$Ligand NO is 3 e^{-} donar hence three CO ligands can be substituted by two NO ligands.$

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