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Q.

If [Cu(H2O)4]2+ absorbs a light of wave length 600 nm for d-d transition, then the value of octahedral crystal field splitting energy for [Cu(H2O)6]2+ will be____×1021J [Nearest integer]
(Given:h=6.63×1034Js andC=3.08×108ms1)

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answer is 766.

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Detailed Solution

Δt=hcλ=6.63×1034×3.08×108600×109
=3.4034×1019J=340.34×1021J

Δt=49Δ0Δ0=94Δt=94×340.34×1021
=765.765×1021=766×1021

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