Q.

If E10,E20andE30  are standard oxidation potentials for Fe|Fe2+,Fe2+|Fe3+and  Fe|Fe3+, then E30=E20+2E10n. The value of n is……….

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answer is 3.

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Detailed Solution

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FeFe2++2e;E10

Fe2+Fe3++e;E10

Adding (1) and (2), we have FeFe3++3e;E10

ΔG10=2FE10, ΔG20=1FE20, ΔG30=ΔG10+ΔG20

3FE30=2FE101FE20

E30=E20+2E103

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