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Q.

If equilibrium constants of reaction, N2+O22NO is  K1 

and 12N2+12O2NO is K2, then

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a

K1=2K2

b

K1=12K2

c

K1=K2

d

K2=K1

answer is B.

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Detailed Solution

N2+O22NO           ..(i)

12N2+12O2NO           …(ii)

For equation number (i) 

K1=[NO]2N2O2                   …(iii)

For equation number (ii) 

K2=[NO]N21/2O21/2         …(iv)

From equation (iii) and (iv) it is clear that

K2=K11/2=K1;  Hence, K2=K1

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