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Q.

If excess of AgNO3 solution is added to 100 mL of a 0.024 M solution of dichlorobis (ethylene diamine cobalt (III) chloride, how many mol of Agcl be precipitated?

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a

0.0016

b

0.0024

c

0.0048

d

0,0012

answer is C.

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Detailed Solution

Each complex molecule only releases one  CI, which precipitates as  Agcl 

100 mL of 0.024M complex =0.024mol/L×100mL1000mL/L=0.0024mol

The number of moles of Agcl formed = the number of moles of complex 0.024M mol

CoCl2(en)2Cl    +AgNO3        AgCl    100×0.024=2.4    2.4mol

Hence correct option is C.

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