Q.

If following proceed in forward side,

HNO2+HFH2F++NO2 CH3COOH+HFF+CH3COOH2+ H2O+CH3COOHH3O++CH3COO

then, the increasing order of acidic strength is

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a

HNO2<CH3COOH<HF<H2O

b

HNO2<HF<CH3COOH<H2O

c

HNO2<HF<H2O<CH3COOH

d

H2O<CH3COOH<HF<HNO2

answer is A.

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Detailed Solution

HNO2 is proton donor and is thus stronger acid than HF.
HF is proton donor and is thus stronger acid than CH3COOH.
CH3COOH is proton donor and is thus stronger acid than H2O.

HNO2>HF HF>CH3COOH CH3COOH>H2O

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If following proceed in forward side,HNO2+HF⇌H2F++NO2− CH3COOH+HF⇌F−+CH3COOH2+ H2O+CH3COOH⇌H3O++CH3COO−then, the increasing order of acidic strength is