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Q.

If initial concentration is reduced o 1/4^th in a zero order reaction, the time taken for half the
reaction to complete

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a

Becomes 4 times

b

Remains same

c

Becomes one – fourth

d

Doubles

answer is C.

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Detailed Solution

$t = \frac{a}{k}$ for zero order, $t = \frac{1}{4 k} a n d t_{1} = \frac{1}{2 k}, ∴ t_{1} = 2 t$

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If initial concentration is reduced o 1/4th in a zero order reaction, the time taken for half thereaction to complete