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Q.

If Ksp of Ag2CO3 is 8×1012, the molar solubility of   Ag2CO3 in 0.1 M AgNO3 solution is

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a

8×1010M

b

8×1012M

c

8×1011M

d

8×1013M

answer is C.

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Detailed Solution

Ag2CO32Ag++CO32    AgNO3Ag++NO3
S            (2S+0.1)  S     0.1         0.1       0.1
KSP=[Ag+]2[CO32]
8×1012=(2S+0.1)2[S]  8×1012=(0.1)2[S]    [S<<0.1 So ‘2S’ is negligible]
S=8×1012102=8×1010

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