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Q.

If molecular axis is X then which of the following overlapping will form π bond?

pz+pz,px+px,px+py,s+pz,py+py

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answer is 2.

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Detailed Solution

P-P overlap and P-P bond are terms used to describe the mutual overlapping of two atoms' half-filled P orbitals. If the overlapping occurs along the internuclear axis, the bond is referred to as a "bond," and if it occurs laterally, it is referred to as a "bond." Pz orbitals overlap end to end because they are along the axis, whereas Px and Py orbitals overlap sideways because they are not,

pz+pz,py+py

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