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Q.

If the bond energies of  HH,BrBrandHBr are 433, 192 and 364 kJ mol-1  respectively the ΔH0 for the reaction  H2(g)+Br2(g)2HBr(g) is 

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a

-261kJ

b

+103 kJ

c

+261kJ

d

-103kJ

answer is D.

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Detailed Solution

H2(g)+Br2(g)2HBr(g)  Enthalpy change for this reaction will equal to the difference in the energy consumed for breaking bonds of reactions and energy released when bonds of products are made
Enthalpy=(Sum of bond energies broken) - (sum of bond energies formed). 
 ΔH0=(BE)reaction(BE)product =(433+192)(2×364) =625728=103kJ
 
 

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