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Q.

If the equivalent conductance of 1 M benzoic acid is 12.8 ohm1cm2eq1 and if the conductance of benzoate ion and H+ ions are 42 and 288.42 ohm1cm2eq1 respectively, its degree of dissociation is

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a

39%

b

3.9%

c

0.35%

d

0.039%

answer is B.

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Detailed Solution

α=ΛmΛ0m=12.8(42+288.42)=0.0387

Percentage dissociation
= 0.0387 × 100  3.9%

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If the equivalent conductance of 1 M benzoic acid is 12.8 ohm−1cm2eq−1 and if the conductance of benzoate ion and H+ ions are 42 and 288.42 ohm−1cm2eq−1 respectively, its degree of dissociation is