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Q.

If the ionic product of Ni(OH)2 is 1 .9 x 10-15, then the molar solubility of Ni(OH)2 in 1.0 M NaOH is

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a

1.9×1018  M

b

1.9×1013  M

c

1.9×1015 M

d

1.9×1014 M

answer is C.

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Detailed Solution

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NaOHNa++OH

                      CM       CM
Ni(OH)2Ni2++2OH

   X                X            X
 Total OH=x+C Ksp=Ni2+OH2=x(x+C)2 =xx2+2Cx+C2  or Ksp=xC2 (neglecting higher powers of x )  x=KspC2=1.9×1015(1)2=1.9×1015M

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