Q.

If the ionic product of Ni(OH)2 is 1.9×1015, the molar solubility of Ni(OH)2 in 1.0 M NaOH is

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a

1.9×10-14 M  

b

1.9×10-18 M  

c

1.9×10-13 M  

d

1.9×10-15 M  

answer is C.

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Detailed Solution

Ni(OH)2Ni2++OH-

[Ni2+] = s, [OH-] = 2s

NaoHNa++OH-

[Na+]= 1, [OH-] = 1

Total [OH-] = 2s + 1

Ksp=[Ni2+][OH-]2

= s (2s + 1)

As Ksp  is small, 2s<<1

Ksp=s×12

1.9×1015 = s

Hence, the correct option is option (C) 1.9×10-15 M.

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