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Q.

If the KSP  of AgCl is 8 × 10-12, the molar solubility of AgCl in 0.1M AgNO3 solution is

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a

8 × 10-12 M

b

8 × 10-13 M

c

8 × 10-10 M

d

8 × 10-11 M

answer is D.

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Detailed Solution

AgClAg++Cl
(S+0.1) S
AgNO3  Ag++NO30.1M        0.1 0.1
S<<0.1 hence “S” can be neglected.
KSP=0.1(S) S=KSP0.1=8×1012101=8×1011M

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