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Q.

If the magnetic moment of a dioxygen species is 1.73 B.M, it may be 

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a

O2 or O2+

b

O2 or O2+

c

O2 or O2

d

O2,O2 or O2+

answer is A.

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Detailed Solution

Number of unpaired electrons:

μ=n(n+2) 1.73=n(n+2) n=1

Species that has only one unpaired electron, has 1.73 BM.

O2- has 17 electrons:

σ1s2σ∗1s2 σ 2s2σ∗2s2σ2pz2  π2px2=π2py2 π2px22py1
One unpaired electron

O2+ has 15 electrons.

σ1s2σ∗1s2 σ 2s2σ∗2s2σ2pz2  π2px2=π2py2 π2px12py0

One unpaired electron

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