Q.

If the magnetic moment of a dioxygen species is 1.73B.M, it may be :

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a

O2or O2+

b

O2 or O2+

c

O2,O2or O2+

d

O2 or O2

answer is D.

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Detailed Solution

 μ=n(n+2)=1.73B.M n(n+2)=1.73 (n(n+2))2=(1.73)2 n(n+2)=3 n=1 One unpaired electron  In optionB: O2has17electrons. σ1s2σ1s2σ2s2σ2s2σ2pz2π2px2=π2py2 π2px2=π2py1 One unpaired electron O2+has15electrons. σ1s2σ1s2σ2s2σ2s2σ2pz2π2px2=π2py2 π2px1=π2py0 One unpaired electron O2 and  O2+  both contain One unpaired electron. i.e, n=1 and  have a magnetic moment of 1.73 B.M.

Hence, the correct option is option (D) O2or O2+.

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