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Q.
If the mass of proton is doubled and that of theneutron is halved, the molecular weight of CO2 consisting of only C12 and O16 atoms, will:
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a
not change
b
increase by 50%
c
increase by 25%
answer is B.
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Detailed Solution
To determine the impact of altering the masses of protons and neutrons on the molecular weight of CO2, let’s break the solution into clear steps:
1. Standard Molecular Weight of CO2
The molecular weight of CO2 is calculated based on the atomic masses of carbon and oxygen:
- Carbon (C12): Atomic number = 6 (6 protons and 6 neutrons).
- Oxygen (O16): Atomic number = 8 (8 protons and 8 neutrons).
For CO2:
- Total protons in CO2: 6 + 8 + 8 = 22.
- Total neutrons in CO2: 6 + 8 + 8 = 22.
Thus, the molecular weight of CO2 is:
Molecular Weight = 44.01 g/mol.
2. New Molecular Weight with Altered Masses
- New mass of a proton: 2 times its original mass.
- New mass of a neutron: 0.5 times its original mass.
The total new mass of CO2 is calculated as:
New total mass = (No. of protons × New mass of proton) + (No. of neutrons × New mass of neutron)
Substituting the values:
New total mass = (22 × 2) + (22 × 0.5)
New total mass = 44 + 11 = 55 g/mol.
3. Change in Molecular Weight
The increase in molecular weight is:
Increase in mass = 55 - 44 = 11 g/mol.
The percentage increase in molecular weight is:
Percentage Increase = (Increase in mass / Original Molecular Weight) × 100
Percentage Increase = (11 / 44) × 100 = 25%.
Conclusion
The molecular weight of CO2 increases by 25% when the mass of a proton is doubled and that of a neutron is halved.