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Q.

If the molecular wt. of Na2S2O3 and I2 are M1 and M2 respectively, then what will be the equivalent wt. of Na2S2O3 and I2 in the following reaction? Question Image 

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a

M1, M2/2

b

M1, M2

c

2 M1, M2

d

M1, 2M2

answer is B.

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Detailed Solution

\large \mathop {2{S_2}}\limits^{ + 2} O_3^{ - 2}\; + \;\mathop {{I_2}}\limits^0 \; \to \;\mathop {{S_4}}\limits^{ + 2.5} O_6^{ - 2}\; + \;2\mathop {{I^ - }}\limits^{ - 1}


 

In hypo two sulphur atoms per molecule is undergoing change in oxidation state.

Valency factor (n-factor) =|2×2.5-2×2|=1

ENa2S2O3=M11=M1

Valency factor of I2|2-1-20|=2

EI2=M22

 

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