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Q.

If the pressure of H2 gas is increased from 1 atm to 100 atm. Keeping H+ concentration constant at 1 M, the voltage of hydrogen half cell at 25oC will be 

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a

0.0591 V

b

0.59 V

c

0.0295 V

d

0.118 V

answer is A.

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Detailed Solution

H2(1 atm)2H+(1M)+2e

EH2/H+=EH2/H+o0.05912log[H+]2PH2                   =0.000.05912log(1)21=0.00V

Now, pressure is increased from 1 atm to 100 atm

EH2/H+=EH2/H+o0.05912log[H+]2PH2                  =00.05912log(1)2100                  (  [H+]is constant )                  =0.05912log102=0.0591V

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If the pressure of H2 gas is increased from 1 atm to 100 atm. Keeping H+ concentration constant at 1 M, the voltage of hydrogen half cell at 25oC will be