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Q.

If the solubility of Ag2SO4 in 10-2 M Na2SO4 solution be 2 x10-8 M then Ksp of Ag2SO4 will be:

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a

32×1024

b

16×1018

c

32×1018

d

16×10-24

answer is B.

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Detailed Solution

Na2SO4=102m

Solubility of  Ag2SO4 =2×108m=s

Ksp of Ag2SO4 = ?

Na2SO42Na++SO2

Ag2SO4ag++SO42

S=2×108Ag+=4×108

Ksp=[Ag]2SO24

Ksp=16×1016×102

=2×2×1082102=16×10162=16×1018

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