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Q.

If the standard electrode potential of Cu2+/Cu electrode is 0.34 V, what is the electrode potential at 0.01 M concentration of Cu2+?T=298K

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a

0.399 V

b

0.281 V

c

0.222 V

d

0.176 V

answer is B.

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Detailed Solution

Reduction of copper 

Cu2++2e-Cu

Electrode potential can be calculated using Nernst equation: 

Ecell=Ecello-0.0591nlog 1[Cu2+]          =0.34-0.05912log 1102 Ecell=0.281 V

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