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Q.

If the synthesis of ammonia from Haber's process is carried out with exactly the same starting conditions (of partial pressure and temperature) but using D2 (deuterium) in place of H2. Then

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a

the equilibrium will be disturbed

b

Use of isotope in reaction will not produce ammonia

c

At equilibrium rate of forward reaction will be greater than the rate of reverse reaction

d

the composition of reaction mixture will remain same at equilibrium.

answer is B.

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Detailed Solution

The reaction mixtures starting either with H2 or D2 reach equilibrium with the same composition, except that D2 and ND3 are present instead of H2 and NH3.

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