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Q.

If the total vapour pressure of the liquid mixture A and B is given by the equation : P=180 XA+90 then the ratio of the vapour pressure of the pure liquids A and B is given by: 

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a

3 : 1

b

3 : 2

c

6 : 2

d

4 : 1

answer is C.

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Detailed Solution

As we know 

PT=PAoXA+PBoXB=PAoXA+PBo(1XA)=(PAoPBo)XA+PBo    .....(1)

But from question, PT=180XA+90       .....(2)

Equating equation (1) and (2) 

PAoPBo=180PBo=90;PAo=180+90=270PAoPBo=27090=3:1

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