Q.

If the z-axis is internucleus axis, which of the following orbital can't form δbond?

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a

All can form

b

dx2y2

c

dxy

d

dz2

answer is A.

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Detailed Solution

The δbond, is only generated by the face-to-face overlap of two parallel d orbitals and has a very different symmetry from the other two types of bonds with regard to the internuclear axis

The parameters for forming a delta bond are not satisfied by the dz2 orbital.
Thus, the dz2 orbital cannot form the δ bond.

Hence, the option A is correct.

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