Q.

If three faradays of electricity are passed through the solutions of AgNO3,CuSO4 and AuCl3, the molar ratio of the cations deposited at the cathodes will be

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a

1:1:1

b

3:2:1

c

1:2:3

d

6:3:2

answer is D.

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Detailed Solution

Ag++e-Ag  1 F= 1 mole Ag  3F= 3 molesAg  

 

Cu2++2e-Cu 2F= 1 mole Cu  3 F= 32 mole Cu  

Au3++3e-Au 3F= 1 mole Au 

Ratio of Ag:Cu :Au ::3: 32:1 = 6:3:2

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If three faradays of electricity are passed through the solutions of AgNO3,CuSO4 and AuCl3, the molar ratio of the cations deposited at the cathodes will be