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Q.

If three faradays of electricity is passed through the solutions of AgNO3 , CuSO4 and AlCl3 the mole ratio of cations deposited at the cathodes will be

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a

1 : 1 : 1

b

6 : 3 : 2

c

3 : 2 : 1

d

1 : 2 : 3

answer is A.

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Detailed Solution

AgNO3Ag++NO3; Ag++eAg
1 F of electricity deposits 1 mole Ag
3 F gives 3 moles
CuSO4Cu+2+SO42; Cu+2+2eCu
2 F of electricity deposits 1 mole of Cu
3 F gives 1.5 moles
AuCl3Au+3+3Cl; Au+3+3eAu
3 F electricity deposits 1 mole of Au
 ratio of No. of moles of Ag, Cu & Au deposited = 3 : 1.5 : 1 (or) 6 : 3 : 2

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