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Q.

If we replace all the fluoride  ligands from  [CoF6]3 by oxalate ligand without changing the oxidation state and co-ordination number of central metal atom or ion, then, peredict which of the following increases in the newly formed complex.

a)  Δ0  b) Number of  t2g electrons  c) Number of eg electrons
d) Number of optical isomers   e) Number of geometrical isomers,
f) EAN value   g) Stability of complex 

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answer is 4.

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Detailed Solution

[CoF6]3[Co(C2O4)3]3-

W.F.L                  S.F.L

t2g4  eg2         t2g6  eg0

Δ0t2g, optical isomers & Stability of complex increases.

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